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On the Paramagnetic Impurity Concentration of Silicate Glasses from Low-Temperature Physics

机译:低温物理硅酸盐玻璃的顺磁杂质浓度研究

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摘要

The concentration of paramagnetic trace impurities in glasses can be determined via precise SQUID measurements of the sample’s magnetization in a magnetic field. However, the existence of quasi-ordered structural inhomogeneities in the disordered solid causes correlated tunneling currents that can contribute to the magnetization, surprisingly, also at the higher temperatures. We show that taking into account such tunneling systems gives rise to a good agreement between the concentrations extracted from SQUID magnetization and those extracted from low-temperature heat capacity measurements. Without suitable inclusion of such magnetization contribution from the tunneling currents, we find that the concentration of paramagnetic impurities gets considerably over-estimated. This analysis represents a further positive test for the structural inhomogeneity theory of the magnetic effects in the cold glasses.
机译:玻璃中顺磁性痕量杂质的浓度可以通过对样品在磁场中的磁化强度进行精确的SQUID测量来确定。但是,无序固体中存在准有序的结构不均匀性会引起相关的隧穿电流,令人惊讶的是,即使在较高温度下,其也可能导致磁化。我们表明,考虑到这种隧穿系统,可以使从SQUID磁化强度中提取的浓度与从低温热容测量中获得的浓度之间达成良好的一致性。如果没有适当地包含隧穿电流产生的这种磁化贡献,我们发现顺磁性杂质的浓度被大大高估了。该分析代表了对冷玻璃中磁效应的结构不均匀性理论的进一步肯定检验。

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